Wednesday June 26th – Thursday June 27th, 2013: As part of the Department of Chemistry & Biochemistry’s outreach efforts through the REU Program, Casey and 5 JMU professors helped run a science…
Electrodes made from pencil lead are attached to a 9V battery to electrolyze various solutions. Oxidation occurs and the anode and reduction occurs at the cathode. When a solution of tin (II) chloride is electrolyzed tin metal and chlorine gas are produced:
SnCl2 (aq) → Sn (s) + Cl2 (g)
When a solution of copper (II) chloride is electrolyzed copper metal and chlorine gas are produced:
CuCl2 aq) → Cu (s) + Cl2 (g)
A reaction between two white solids occurs when lead nitrate and potassium iodide are shaken forcefully producing a mixture of yellow and white solid products. The reaction occurs almost instantaneously when aqueous solutions of these compounds are mixed, precipitating yellow lead iodide.
Pb(NO3)2 + 2KI → PbI2 + 2KNO3
When magnesium ribbon is placed in hydrochloric acid, hydrogen gas is produced causing the mixture to bubble.
Mg (s) + 2HCl (aq) → MgCl2 (aq) + H2 (g)
If they hydrogen gas is collected, it can be ignited to demonstrate the potential safety concerns of an evolved gas.
H2 (g) + O2 (g) → H2O (g)
As two rusty cannon balls (one covered in aluminum foil) are smashed together, sparks and a cracking sound are produced.
Fe2O3 (s) + 2Al (s) → Al2O3 (s) + 2Fe (s)
When 50mL of water are added to 50mL of ethanol in a 100mL graduated cylinder, there are only ~97mL of liquid. Ethanol and water molecules are attracted to each other through hydrogen bonding. The two molecules pack closer together with each other than they do with just themselves.
When magnesium is ignited, it is readily oxidized by oxygen in the air producing an incredibly bright light and intense heat.
2Mg (s) + O2 (g) → 2MgO (s)
In this demo, baking soda and vinegar are mixed in a plastic storage bag. The reaction container is massed before and after the reaction for students to see the Law of Conservation of Mass in action.
NaHCO3 (s) + CH3COOH (aq) →CO2 (g) + H2O (l) + CH3COONa (aq)
In this demo a ping pong ball with a hole along the seam is submerged in liquid nitrogen (-196⁰C) to fill it. When removed, the nitrogen in the ball boils and is forced out of the hole in a stream. The stream, which comes out at an angle, causes the ball to spin away from the stream. The “stream” that we see is condensed water vapor, not nitrogen gas.
In this “trash-to-treasure” activity, polystyrene clamshell containers (#6 plastic) are used to make hard plastic art pieces. When polystyrene clamshell containers are produced, the material is heated and stretched into a mold, thus locking the material in an extended state. When this material is heated again, it returns to its unstretched size and shape. This property can be utilized to create a range of crafts, including buttons, key chains, luggage tags and jewelry. If students mass their plastic before and after, this could also be tied to the Law of Conservation of Mass.